I like threads like this because I might learn something. Anyhow, to answer your question, at a guess, and of course
having a do with Saturday wine......what makes you think the frame was sand blasted to shiny steel then immediately in
the seconds after sprayed? My guess is that it was left for a hand full of days or weeks before being sprayed and hence,
oxidisation / darkening happened which any primer should have taken care of to do it's job as a bonding agent.
I'm an engineer, not a molecular level mentalists.